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Chemistry Paper 2

Whats the process used in cracking?

Heavy fraction heated to vaporised hydrocarbons, then it's passed over a hot catalyst or mixed with steam and heated to a very high temperature

Complete combustion of a hydrocarbon products are:

Carbon dioxide and water

Test for carbon dioxide

Turns limewater cloudy when carbon dioxide is bubbled through it

Test for water

Blue cobalt chloride paper pink

General reaction of alkenes and water

Alkene+water => alcohol

Alkenes reacting with bromine

Alkene will take the colour out of bromine

Alkenes reacting with hydrogen

60oC in the presence of a Nickel catalyst - increases boiling point

Alcohol functional group

-OH

Carboxylic acid functional group

-COOH

Esters functional group

-COO- (replace H atom in -COOH with a hydrocarbon)

What are the 2 ways to make an alcohol

-Alkene with steam in the presence of a catalyst
-fermentation of sugars with yeast in warm, anaerobic conditions

Complete combustion of alcohols

Alcohol+oxygen => carbon dioxide+water

Alcohol reacting with sodium

Sodium+ethanol => sodium ethoxide+hydrogen

Oxidation of alcohols

Alcohol+oxidising agent => carboxylic acid+water

How to make esters

Carboxylic acid+alcohol => ester+Water (acid catalyst)

What are the two amino acid functional groups?

-the amine group, - NH2
-the carboxylic group, - COOH

-simplest amino acid is glycine

Whats a mixture designed to be a useful product?

Formulation

Test for hydrogen

'squeaky pop test', lighted splint 'pops'

Test for oxygen

A glowing splint relights

Test for chlorine

Damp blue litmus paper turns white (as it gets bleached)

Test for carbonates

Add dilute acid - produces CO2

Test for Halides

Add nitric acid, then add silver nitrate solution - precipitate of silver halide forms (chlorine=white, bromide=cream, iodide=yellow)

Test for sulfates

Add hydrochloric acid, add barium chloride solution - produces white precipitate of barium sulfate

Flame test for lithium

Crimson

Flame test for Sodium

Yellow

Flame test for Potassium

Lilac

Flame test for Calcium

Orange-red

Flame test for Copper

Green

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