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SL Soichiometry

Moles (mol)

using large groups allows us to work with measurable masses when we convert moles to mass.
Avogadro's constant = 6.02 x 10^23 particles (in one mol)

Molar mass

mass of 6.02 x 10^23 particles of a substance. g/mol. Using moles allows us to measure amounts of substances regardless of atom size. you are measuring quanitity.

Empirical Formula

The formula of a chemical compound in its simplest form.

Conservation of Matter

Matter cannot be created nor destroyed

Atom Economy

Evaluates the conservation of natural resources for synthetic and industrial processes. The higher the percentage, the better (the less waste produced).

%AE = (molar mass of atoms of desired product / molar mass of reactants) x100

Atom Economy: Green chemistry

sustainable design of chemical products and chemical processes. aims to minimize the use and generation of chemicals that are hazardous to human health and the environment.

n=

m/M

c=

n/V

concentration

mol OR g dm^-3

Volume

dm^3

molar concentration=

c/M (this is basically either g dm^-3 OR mol dm^-3)

Diluting a solution equation

C1V1=C2V2

Dilution Factor=

10/100 = 10x less concentrated.
ex.

solution 1=0.01 mol dm^-3

solution 2=0.001 mol dm^-3

and so on...

Spectrophotometry

measurement of the intensity of radiation used to determine the concentration of coloured solutions. A spectrophotometer produces light at certain wavelengths which passes through small sample of solution, and a photodetector measures the light intensity that is transmitted and converts it to absorbance.
KNOW THE GRAPH!!

Acid + base =

salt + H2O

Gas Laws STP

P = 100kPa
T = 273K

Vm = 22.7dm^3 mol^-1

n (gas)=

V/Vm

Vm

dm^3 mol^-1

Ideal Gas Laws

1. spaces between particles are bigger than the particles
2. no intermolecular forces except when they collide

3. kinetic energy is proportional to temperature

4. no energy lost when collisions happen

Pressure increases when

volume decreases and temperature increases

Boyles Law

P1V1 = P2V2 (T is constant). Pressure increases, volume decreases

P and V units

pascals and m^3 (or dm^3)

T units

always in K.
K= degrees in C + 273

Charles Law

T1V2=T2V1 (temp increases volume increases)

Gay-Lusacs Law

T1P2=T2P1 (temp increases, pressure increases)

combined gas law equation

(P1V1)/T1 = (P2V2)/T2

R

8.31 dm^3 *kPa K^-1 mol^-1

Ideal Gas Law equation is

PV = nRT

Real Gases two points

1. the volume of the gas particles are not negligible: real gases travel shorter distances and collide more frequently (more pressure)
2. there are no attractive forces between particles: slower speed and less pressure

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